QUOTE (Urchinhead @ Nov 19 2009, 11:35 AM)

pH does not measure alkalinity. pH tells you how base or acidic your system is. Low pH means acidic and higher pH means base. Both extremes are bad. The animals we keep like a more base than acidic environment hence the desire to keep it between 8.2 and 8.6.
That said DO NOT CHASE PARAMETERS! Yes I am shouting. You will only get into trouble if you keep dumping stuff in the tank trying to get to that perfect pH range.
^^^ Best advice in here yet.
Let me share some experience... My 30g tank (before I tore it down and moved last year) I was having a very low pH issue. pH was 7.51 by night, and only 7.8 by day... I tested my alk and it was at 4.3 dKH!! Remember, normal is between 9-12 for our tanks (though the ocean is at 7-9, but there's a reason for keeping it higher in a tank). That said, I dosed the alk part of B-Ionic for a couple months, and eventually my pH was at around 7.9 by night and 8.2 by day. My alk also rose considerably of course and all was well.
Come right to right now, I've been worried for my pH peaking at 8.54 by day and down to 8.2 by night. Apparently 8.5-8.6 isn't at all bad for a daytime peak, so I'm good there. I ASSumed that if my pH is high, then my alk should be fine too, right? How WRONG I could be. I tested 2 nights ago and my alk is 5.44 dKH...

Ca is 560 and MG is around 1300. CO2 concentration in my house is VERY low, hence the high pH level. So basically in short, pH will not determine your alk or vice versa. They can just coincidentally reflect eachother at times.
My advice is to check your alk ASAP. If it's low (which I'm guessing it probably is) then raise is using alk solution, or better yet use some kalkwasser. Monitor your alk level DAILY once you start dosing alk or kalk as well as your pH level of course. And also check your Mg and Ca levels too regularly as those DO go hand in hand with alk. Good luck!